backbonding ligand
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Ligand field theory — (LFT) describes the bonding in coordination complexes. [Schläfer, H. L.; Gliemann, G. Basic Principles of Ligand Field Theory Wiley Interscience: New York; 1969] It represents an application of molecular orbital theory to transition metal… … Wikipedia
Π backbonding — π backbonding, also called π backdonation, is a concept from chemistry, in which electrons move from an atomic orbital on one atom to a π* anti bonding orbital on another atom or ligand. It is especially common in the organometallic chemistry of… … Wikipedia
Metal L-edge — Figure 1: L3 and L2 edges of [CuCl4]2 … Wikipedia
d electron count — The d electron count is a chemistry formalism used to describe the electron configuration of the valence electrons of a transition metal center in a coordination complex.[1][2] The d electron count is an effective way to understand the geometry… … Wikipedia
Cyclopentadienyl complex — Zirconocene dichloride, a cyclopentadienyl complex A cyclopentadienyl complex is a metal complex with one or more cyclopentadienyl groups (C5H5−, abbreviated as Cp−). Based on the type of bonding between the metals and the cyclopentadienyl]]… … Wikipedia
Palladium(II) acetate — Chembox new Name = Palladium(II) acetate ImageFile = Palladium(II) acetate.jpg ImageName = Palladium(II) acetate IUPACName = Palladium(II) acetate OtherNames = Palladium diacetate hexakis(acetato)tripalladium bis(acetato)palladium Section1 =… … Wikipedia
Transition metal carbene complex — A transition metal carbene complex is a organometallic compound featuring a divalent organic ligand. The divalent organic ligand coordinated to the metal center is called a carbene. Carbene complexes for almost all transition metals have been… … Wikipedia
Oxidative addition — and reductive elimination are two important and related classes of reactions in organometallic chemistry.[1][2][3] Oxidative addition is a process that increases both the oxidation state and coordination number of a metal centre. The oxidative… … Wikipedia
Ziegler-Natta catalyst — A Ziegler Natta catalyst is a reagent or a mixture of reagents used in the production of polymers of 1 alkenes (α olefins). Ziegler Natta catalysts are typically based on titanium compounds and organometallic aluminium compounds, for example… … Wikipedia
Organoruthenium chemistry — is the chemistry of organometallic compounds containing a carbon to ruthenium chemical bond.[1] The interest is mostly academic although several organoruthenium catalysts are of commercial interest. The chemistry has many similarities with… … Wikipedia
