thiolate

thiolate
any derivative of a thiol in which a metal atom replaces the hydrogen attached to sulfur RSH => RSM

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  • Thiolate — von oben nach unten: Allgemeine Formel eines Natriumthiolates und eines Lithiumthiolates. Formel von Natriumthiomethylat, Lithiumthiomethylat und Natriumthiophenolat. Das Thioalkoholat Anion ist blau gekennzeichnet. R ist ein Organyl Rest (Alkyl… …   Deutsch Wikipedia

  • Thiolate — Exemple de thiolates. De hat en bas : formule générale des thiolates, un thiolate de lithium, un thiolate de sodium, thiométhylate de sodium, thiométhylate de lithium et thiophénolate de sodium. L anion thiolate en bleu, R représente un… …   Wikipédia en Français

  • thiolate — tioliatas statusas T sritis chemija formulė RSM atitikmenys: angl. mercaptide; thiolate rus. меркаптид; тиолят …   Chemijos terminų aiškinamasis žodynas

  • Disulfide bond — In chemistry, a disulfide bond (Br.E. disulphide bond) is a covalent bond, usually derived by the coupling of two thiol groups. The linkage is also called an SS bond or disulfide bridge. The overall connectivity is therefore R S S R. The… …   Wikipedia

  • Thiol-disulfide exchange — is a chemical reaction in which a thiolate group mathrm{S}^{ } attacks a sulfur atom of a disulfide bond S S . The original disulfide bond is broken, and its other sulfur atom (green atom in Figure 1) is released as a new thiolate, carrying away… …   Wikipedia

  • Réaction de Herz — La Réaction de Herz, du nom du chimiste Richard Herz, la conversion de dérivés de aniline (1) en sels de Herz (2) avec du dichlorure de disoufre, suivi par une hydrolyse du dit sel (2) en le thiolate de sodium correspondant (3) [1]: Sommaire …   Wikipédia en Français

  • Thiol — with a blue highlighted sulfhydryl group. In organic chemistry, a thiol (   …   Wikipedia

  • Isopenicillin-N synthase — (IPNS) is a non heme iron dependent enzyme belonging to the oxidoreductase family. This enzyme catalyzes the formation of isopenicillin N from δ (L α aminoadipoyl) L cysteinyl D valine (LLD ACV).:N [(5S) 5 amino 5 carboxypentanoyl] L cysteinyl D… …   Wikipedia

  • organosulfur compound — ▪ chemical compound Introduction also spelled  organosulphur compound , also called  organic sulfur compound   a subclass of organic substances that contain sulfur and that are known for their varied occurrence and unusual properties. They are… …   Universalium

  • Cysteine — Not to be confused with cystine. CYS redirects here. CYS may also refer to California Youth Symphony. L Cysteine …   Wikipedia

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