deracemization

deracemization
The conversion of a racemate into a pure enantiomer or into a mixture in which one enantiomer is present in excess, or of a diastereoisomeric mixture into a single diastereoisomer or into a mixture in which one diastereoisomer predominates

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  • Carroll rearrangement — The Carroll rearrangement is a rearrangement reaction in organic chemistry and involves the transformation of a β keto allyl ester into a α allyl β ketocarboxylic acid. [Carrol, M. F. 131. Addition of α,β unsaturated alcohols to the active… …   Wikipedia

  • Transposición de Carroll — La Transposición de Carroll es una reacción orgánica que consiste en la transformación de un β cetoalil éster en un ácido α alil β cetocarboxílico.[1] Esta reacción orgánica está precedida por una descarboxilación y el producto final es una γ, δ… …   Wikipedia Español

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